王坡煤矿煤层顶板稳定性主控因素分析

煤炭开采过程中极易发生顶板事故。基于王坡煤矿的地质条件，利用钻孔、井下钻探、物探、生产揭露资料，分别对该矿煤层顶板沉积特征、煤层顶板岩石结构特征进行系统分析研究，通过实验室室内测试，获取了煤层顶板岩石抗压强度、泊松比、坚固性系数、黏聚力等物理力学性质指标，最终确定了影响煤层顶板稳定性相关因素；运用层次分析法确定影响因素的权重值，得出岩石力学性质是影响煤层顶板稳定性的主控因素。研究可为类似煤矿顶板稳定性因素分析提供借鉴。     

不同含量低污染水对人工湿地中细菌的影响研究

探究水平流人工湿地(HFCW)系统处理低污染水过程中,相同COD/ρ(TN)下不同碳氮含量对细菌群落结构的影响。结果表明,进水为较高碳氮含量的HFCW(HF1)和进水为较低碳氮含量的HFCW(HF2)对COD和TN的去除效率具有一定的差异,HF1和HF2对COD的去除效率分别为48.26%和28.89%,对TN的去除率分别为79.06%和81.87%。HF1中细菌的丰富度和多样性均高于HF2,HF1中富集的优势细菌为Chloroflexaceae、Comamonadaceae和Rhodocyclaceae,均具有异养反硝化功能,HF2中富集的优势细菌为Xanthomonadaceae和Rhodocyclaceae,其中Xanthomonadaceae具有自养反硝化功能。COD、NH4^+-N和NO3^--N对HF1中细菌群落的影响大于对HF2中细菌群落的影响,HF1中COD对细菌群落的影响大于NH4^+-N和NO3^--N。     

Structure variation and energy storage properties of acceptor-modified PBLZST antiferroelectric ceramics

Energy storage capacitors with high recoverable energy density and efficiency are greatly desired in pulse power system. In this study, the energy density and efficiency were enhanced in Mn-modified (Pb_0.93Ba_0.04La_0.02)(Zr_0.65Sn_0.3Ti_0.05)O₃ antiferroelectric ceramics via a conventional solid-state reaction process. The improvement was attributed to the change in the antiferroelectric-to-ferroelectric phase transition electric field (E_F) and the ferroelectric-to-antiferroelectric phase transition electric field (E_A) with a small Mn addition. Mn ions as acceptors, which gave rise to the structure variation, significantly influenced the microstructures, dielectric properties and energy storage performance of the antiferroelectric ceramics. A maximum recoverable energy density of 2.64 J/cm³ with an efficiency of 73% was achieved when x = 0.005, which was 40% higher than that (1.84 J/cm³, 68%) of the pure ceramic counterparts. The results demonstrate that the acceptor modification is an effective way to improve the energy storage density and efficiency of antiferroelectric ceramics by inducing a structure variation and the (Pb_0.93Ba_0.04La_0.02)(Zr_0.65Sn_0.3Ti_0.05)O₃-xMn₂O₃ antiferroelectric ceramics are a promising energy storage material with high-power density.     

Effect of nonsolvent additives on PES ultrafiltration membrane pore structure

Different nonsolvent additives, namely, diethylene glycol, n-butyl alcohol (NBA), and ethylene glycol monomethyl ether, were added into the casting solution (polyethersulfone/dimethylformamide/lithium chloride) to prepare ultrafiltration (UF) membrane via phase inversion. The effects of different additives and their concentration on the pore structure of the prepared UF membrane were studied. The cross-sectional morphology of the membrane was observed via scanning electron microscopy. The addition of nonsolvent additives improved the large-cavity structure of the membrane. When the additive was low-content NBA (1–3 wt %), the membrane pore structure transformed from large-cavity structure to fully sponge-like structure. When the content of additive NBA was 3 wt %, the flux of the prepared UF membrane was 130.45 L (m⁻² h⁻¹), the rejection of PEG20000 was 95.54% and the flux remained high at 4 bar in long-term stability test. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47525.     

不同晶相结构ZrO2负载铜基催化剂用于二乙醇胺脱氢反应

通过制备不同晶相结构〔单斜相(m-ZrO_2)、四方相(t-ZrO_2)和无定型(a-ZrO_2)〕ZrO_2载体,再通过沉积沉淀法制得Cu/m-ZrO_2、Cu/t-ZrO_2和Cu/a-ZrO_2催化剂,分别用于催化二乙醇胺脱氢合成亚氨基二乙酸反应。采用XRD、氮气物理吸附脱附、XPS、H_2-TPR、CO_2-TPD对催化剂的结构进行了表征。结果表明,Cu/m-ZrO_2催化剂界面更加有利于Cu~+/Cu~0稳定存在,具有更多的碱性位点,且抗氧化性较好。在二乙醇胺脱氢反应中,Cu/m-ZrO_2催化剂性能最好,反应时间为2.5 h,亚氨基二乙酸收率为97.64%。     

Alcoholism detection based on Hu moment invariants of event-related potentials

Diagnostic efforts to identify alcoholism are frequently subjective; however, recent technological advances have allowed the automated assessment of objective signals. To improve the performance of the automated classification of patients with alcohol dependence (AD) and controls, we analyzed features of event-related potentials (ERPs) in 72 subjects with AD and 42 controls while the subjects underwent three different visual oddball tasks. In addition to such commonly used morphological features (MFs) as time-domain amplitude and latency components as well as discrete wavelet transform coefficient entropies (WEs), we analyzed Hu moment invariants (HMIs) in this study. Smaller P3 and P2 amplitudes, longer latencies, lower WE values, and lower HMI values were observed for AD subjects relative to those observed for controls. We used a Naïve Bayes algorithm to compare classification accuracies among MFs, WEs, HMIs, combinations of MFs/WEs, and combinations of all three characteristics. We found that HMIs improved the classification accuracy by 17%. Our findings demonstrated that a combined feature analysis of ERPs obtained during a visual oddball task can be a useful and discriminative tool for diagnostic purposes in alcoholism and that HMIs show promise for improving the objective diagnosis of alcoholism and similar diseases.     

Temperature-responsive culture surfaces for insect cell sheets to fabricate a bioactuator

ABSTRACT

For the first time, we have fabricated insect-derived cell sheets by using temperature-responsive culture surfaces having a phase-transition temperature below 25°C. We prepared the temperature-responsive cell culture surfaces (tissue culture polystyrene, TCPS) by grafting a copolymeric gel consisting of hydrophobic N-tert-butylacrylamide (tBAAm) and N-isopropylacrylamide (IPAAm) units. First, to characterize the hydrophilic and hydrophobic properties of the copolymeric gel-grafted surfaces, static water contact angles of each surface were measured at various temperatures. By increasing the amount of tBAAm in the grafted copolymeric gel, the transition temperature of the gel was shifted to lower temperatures. At 25°C, the grafted copolymeric gel was dehydrated, and the insect-derived cells (AeAl2 cells) adhered on all the copolymeric gel-grafted surfaces. At 20°C, AeAl2 cells cannot adhere on the P(IPAAm-1.62tBAAm)-TCPS surface (the initial molar ratio of IPAAm and tBAAm (tBAAm?=?1.62 mol%)) better than on other surfaces (TCPS and tBAAm?=?4.88, 8.17 mol%). These two findings implied that the lower critical solution temperature of the copolymeric gel-grafted-TCPS existed from 20°C to 25°C. The laminin-coated P(IPAAm-1.62tBAAm)-TCPS surface showed temperature-dependent cell attachment and detachment properties, while AeAl2 cells were not detached from the extracellular matrix uncoated P(IPAAm-1.62tBAAm)-TCPS surface. AeAl2 cells and insect muscle cells were harvested as the respective sheets.     

Poly(L-lysine)-poly(ethylene glycol) layers with different structure and their influence on silica suspension stability

The effects of the structure of di- and triblock copolymers of poly(L-lysine) – LYS with poly(ethylene glycol) – PEG as well as the length of nonionic fragment in the LYS-PEG macromolecule on the copolymer chains conformation in the adsorption layer formed on the colloidal silica (SiO2) surface were examined. Spectrophotometry and turbidimetry were applied for the determination of copolymer adsorbed amounts and stability coefficients of silica aqueous suspensions. The electrokinetic parameters such as solid surface charge density and zeta potential were also estimated. The adsorption of LYS-PEG was proved to be the highest at pH 10 whereas the lowest adsorption on the solid surface was found for the triblock copolymer with long fragments of LYS at the same pH value.     

Investigations of geometrical structure and morphology of samples made of hard machinable materials after wire electrical discharge machining and vibro‐abrasive finishing

In this article the results concerned influence of processing conditions of the wire electrical discharge machining and vibro‐abrasive machining on the surface layer and morphology of samples made of hard machinable materials used in aircraft industry like: Titanium 5553 β, Inconel 617, Hastelloy X and Magnesium AZ31 have been presented. For this purpose the cubic and cylindrical samples made of hard machinable alloys have been prepared using optimal electric parameters of wire‐cut electrical discharge machining and finally they have been polished using circular vibratory finishing technology and different ceramic shaped stones.     

Unique crystal structures and their applications as materials for Li1+x-yM1-x-3yTix+4yO3 (M = Nb or Ta, 0.07 ≤ x ≤ 0.33, 0 ≤ y ≤ 0.175)

In the Li₂O–M₂O₅–TiO₂ (M = Nb or Ta) system, Li_1+x-yM_1-x-3yTi_x+4yO₃ (LMT) forms with a superstructure known as the M-phase, in which the periodical intergrowth layers are inserted in a matrix having a trigonal structure of LiMO₃. We have been investigating this unique material focusing on its crystal structure, photoluminescence, and electrical properties.First, the formation area of the superstructure was compared between Nb- and Ta- systems and the difference was accurately analyzed.Second, to apply this unique material as a host material of phosphor, we synthesized new phosphors with various emission colors. Red phosphor, having a high PL intensity with an internal quantum efficiency of 98%, was successfully synthesized and used as a host material of the solid solution for the Ta system. Its high value was the result of the large centroid-to-cation distance of the Eu³⁺ position in the [(Li, Eu)O₁₂] polyhedral.Further still, toward application of the unique qualities of an electro-ceramic, we successfully fabricated oriented balk ceramics for the Nb system by slip casting in a strong magnetic field of 12 T. As a result, anisotropic electric properties were found along the c-axis, which were caused by the superstructure. We first clarified the mechanism showing that the anisotropic Qf value was due to anisotropic electron conductivity and anisotropic bonding strength within the superstructure.